Dinitrofluorobenzene → HCID 86613639, compound

HRID 2264341Notes

Reaction equation

C(=O)([O-])[O-].[K+].[K+].F[C:8]1[CH:13]=[CH:12][C:11]([N+:14]([O-:16])=[O:15])=[CH:10][C:9]=1[N+:17]([O-:19])=[O:18].O[C@@H:21]([CH3:27])[C:22]([O:24][CH2:25][CH3:26])=[O:23]>>[N+:17]([C:9]1[CH:10]=[C:11]([N+:14]([O-:16])=[O:15])[CH:12]=[CH:13][C:8]=1[C@H:21]([CH3:27])[C:22]([O:24][CH2:25][CH3:26])=[O:23])([O-:19])=[O:18]

Participants

Reactant 3

HCID 6264Dinitrofluorobenzene

HCID 11430Potassium Carbonate

HCID 92831(L)-ethyl lactate

Product 1

HCID 86613639HCID 86613639, compound

Procedure

In the presence of potassium carbonate, 1-fluoro-2,4-dinitrobenzen was treated with ethyl (2S)-(−)-2-hydroxypropanoate to obtain ethyl (2S)-2-(2,4-dinitrophenyl)propionate.

Sources & evidence

ORD record: ord-5138bbcf73b94f6986d3855128b9b9bf
Source dataset: uspto-grants-2010_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07855198B2

Reaction notes

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