Methacrylic Acid → 2-Propenoic acid, 2-methyl-, (tricyclo[3.3.1.13,7]dec-2-yloxy)methyl ester

HRID 2265780Notes

Reaction equation

HRID 2265780 reaction equation
[C:1]([OH:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].C(N(CC)CC)C.Cl[CH2:15][O:16][CH:17]1[CH:24]2[CH2:25][CH:20]3[CH2:21][CH:22]([CH2:26][CH:18]1[CH2:19]3)[CH2:23]2>O1CCCC1>[CH:18]12[CH2:26][CH:22]3[CH2:21][CH:20]([CH2:25][CH:24]([CH2:23]3)[CH:17]1[O:16][CH2:15][O:5][C:1](=[O:6])[C:2]([CH3:4])=[CH2:3])[CH2:19]2

Participants

5

Reactant 3

HCID 4093Methacrylic AcidHCID 8471TriethylamineHCID 10932491HCID 10932491, compound

Product 1

HCID 231508582-Propenoic acid, 2-methyl-, (tricyclo[3.3.1.13,7]dec-2-yloxy)methyl ester

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent2×

Procedure

6.9 g of methacrylic acid was dissolved in 200 ml of tetrahydrofuran, and 8.0 g of triethylamine was added thereto. Then, the resultant was stirred at room temperature, and 100 ml of tetrahydrofuran having 15 g of 2-adamantyl chloromethyl ether dissolved was dropwise added.

Workup

  1. additionwas dropwise added

Sources & evidence

ORD record
ord-2145fcc7e51f47f5ba156484ec8062fd
Source dataset
uspto-grants-2010_12
Patent number
US07858286B2

Reaction notes

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