Hydroxylamine → p-Chlorobenzylmercaptoacetohydroxamic acid

HRID 2285931Notes

Reaction equation

HRID 2285931 reaction equation
[Cl:1][C:2]1[CH:14]=[CH:13][C:5]([CH2:6][S:7][CH2:8][C:9](OC)=[O:10])=[CH:4][CH:3]=1.[NH2:15][OH:16]>CO>[Cl:1][C:2]1[CH:14]=[CH:13][C:5]([CH2:6][S:7][CH2:8][C:9]([NH:15][OH:16])=[O:10])=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 787HydroxylamineHCID 3311340Methyl 2-(4-chlorobenzylthio)acetate

Product 1

HCID 54399917p-Chlorobenzylmercaptoacetohydroxamic acid

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

A solution of 0.15 mol of methyl 2-(4-chlorobenzylmercapto)-acetate in 50 ml of methanol is mixed with a solution of 0.225 mol of hydroxylamine (base) and 0.15 mol of NaOH3 in 150 ml of methanol.

Sources & evidence

ORD record
ord-81d2853274df44a99243bae0279f314f
Source dataset
uspto-grants-1982_04
Patent number
US04325964

Reaction notes

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