Diethyl oxalacetate → HCID 23463328, compound

HRID 2286422Notes

Reaction equation

HRID 2286422 reaction equation
[Na].C(O[C:5](=[O:14])[CH2:6][C:7]([C:9]([O:11][CH2:12][CH3:13])=[O:10])=O)C.O.[F:16][C:17]([F:22])([F:21])[CH2:18][NH:19][NH2:20]>C(O)(=O)C>[F:16][C:17]([F:22])([F:21])[CH2:18][N:19]1[C:5](=[O:14])[CH2:6][C:7]([C:9]([O:11][CH2:12][CH3:13])=[O:10])=[N:20]1

Participants

5

Reactant 3

HCID 66951Diethyl oxalacetateHCID 5360545SodiumHCID 23463329HCID 23463329, compound

Product 1

HCID 23463328HCID 23463328, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

1 Mole (221 g) of the sodium salt of oxalacetic diethyl ester and 1 mole (224 g) of 2,2,2-trifluoroethylhydrazine hydrate were stirred for 1 hour in 1 l of boiling acetic acid. The mixture was poured out on water and stirred. The product melting at 171° C. was filtered with suction.

Workup

  1. additionThe mixture was poured out on water
  2. filtrationThe product melting at 171° C. was filtered with suction

Sources & evidence

ORD record
ord-3dc6788a4d734aeca8fb7fba33f4a7f8
Source dataset
uspto-grants-1981_05
Patent number
US04266014

Reaction notes

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