Cyanuric chloride → 2-Chloro-4,6-di(2,3,3-trimethyl-2-butyl)amino-s-triazine

HRID 2287154Notes

Reaction equation

HRID 2287154 reaction equation
Cl.[CH3:2][C:3]([NH2:9])([C:5]([CH3:8])([CH3:7])[CH3:6])[CH3:4].[OH-].[Na+].[N:12]1[C:19](Cl)=[N:18][C:16](Cl)=[N:15][C:13]=1[Cl:14]>O>[Cl:14][C:13]1[N:12]=[C:19]([NH:9][C:3]([CH3:4])([CH3:2])[C:5]([CH3:8])([CH3:7])[CH3:6])[N:18]=[C:16]([NH:9][C:3]([CH3:4])([CH3:2])[C:5]([CH3:8])([CH3:7])[CH3:6])[N:15]=1

Participants

5

Reactant 3

HCID 7954Cyanuric chlorideHCID 14798Sodium HydroxideHCID 12321758(1,1,2,2-Tetramethylpropyl)amine hydrochloride

Product 1

HCID 155725772-Chloro-4,6-di(2,3,3-trimethyl-2-butyl)amino-s-triazine

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

6.7 g. (0.044 mole) 2,3,3-trimethyl-2-butylamine hydrochloride and 3.4 g. (0.84 mole) NaOH in 20 ml. water are added to a stirred slurry of 3.6 g. (0.02 mole) cyanuric chloride in 150 ml. water. The reaction mixture is heated at reflux for 21/2 hours, cooled and filtered to give the product, a white solid, m.p. 129°-131° C., 6.5 g.

Workup

  1. temperatureThe reaction mixture is heated
  2. temperatureat reflux for 21/2 hours
  3. temperaturecooled
  4. filtrationfiltered
  5. customto give the product

Sources & evidence

ORD record
ord-33b4002ee02146238e9f32a7d49dc2c0
Source dataset
uspto-grants-1981_05
Patent number
US04269832

Reaction notes

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