Allyl bromide → HCID 21475502, compound

HRID 2292991Notes

Reaction equation

HRID 2292991 reaction equation
[N+:1]([C:4]1[CH:9]=[C:8]([NH2:10])[CH:7]=[CH:6][C:5]=1[NH:11][CH2:12][CH:13]=[CH2:14])([O-:3])=[O:2].[CH2:15](Br)[CH:16]=[CH2:17].C(=O)([O-])[O-].[K+].[K+].[N+]([C:28]1[CH:29]=C(NCCO)C=C[C:33]=1N(CC=C)CC=C)([O-])=O>C(O)C>[N+:1]([C:4]1[CH:9]=[C:8]([N:10]([CH2:29][CH:28]=[CH2:33])[CH2:15][CH:16]=[CH2:17])[CH:7]=[CH:6][C:5]=1[NH:11][CH2:12][CH:13]=[CH2:14])([O-:3])=[O:2]

Participants

6

Reactant 4

HCID 7841Allyl bromideHCID 11430Potassium CarbonateHCID 21475500HCID 21475500, compoundHCID 235000362-Nitro-N~1~-(prop-2-en-1-yl)benzene-1,4-diamine

Product 1

HCID 21475502HCID 21475502, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture consisting of N-(2-nitro-4-aminophenyl)-allylamine (1.9 g, 0.01 mole), allyl bromide (2.4 g, 0.02 mole) and potassium carbonate (2.8 g, 0.02 mole) was boiled under reflux for 7 hours in 20 ml of ethanol. Working up was carried out in the same way as for compound 4. Yellow crystals, melting point 131°-140° C.

Sources & evidence

ORD record
ord-dd728f2852074dec8a9aa9ea94d068ee
Source dataset
uspto-grants-1997_11
Patent number
US05685881

Reaction notes

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