tert-Butanol → tert-Butyl carbonate

HRID 2295781Notes

Reaction equation

HRID 2295781 reaction equation
Cl[C:2]([O:4]CCl)=[O:3].Cl[C:8]([O:10]CCCl)=[O:9].[CH2:14]([OH:20])[CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[C:21]([OH:25])([CH3:24])([CH3:23])[CH3:22]>>[C:2](=[O:3])([O-:4])[O:25][C:21]([CH3:24])([CH3:23])[CH3:22].[C:8](=[O:9])([O-:10])[O:20][CH2:14][CH2:15][CH2:16][CH3:17].[C:2](=[O:3])([O-:4])[O:20][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]

Participants

7

Reactant 4

HCID 6386tert-ButanolHCID 81031-HexanolHCID 123052-Chloroethyl chloroformateHCID 62754Chloromethyl chloroformate

Product 3

HCID 4613278tert-Butyl carbonateHCID 21903821Butyl carbonateHCID 22641129HCID 22641129, compound

Procedure

Chloromethyl chloroformate and chloroethyl chloroformate can be reacted similarly with other alcohols such as t-butanol and hexanol to form 1-chloromethyl (or ethyl) t-butyl carbonate and 1-chloromethyl (or ethyl) +-butyl carbonate and 1-chloromethyl (or ethyl) hexyl carbonate.

Sources & evidence

ORD record
ord-be5857a65bf94b53bcc8bb109a40f638
Source dataset
uspto-grants-1984_01
Patent number
US04426391

Reaction notes

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