1,8,8-Trimethyl-3-oxabicyclo[3.2.1]octane-2,4-dione → 105441-18-7

HRID 2308709Notes

Reaction equation

HRID 2308709 reaction equation
[CH2:1]1[CH:6]([NH2:7])[C:4](=[O:5])[S:3][CH2:2]1.Cl.C[C:10]1([CH3:21])[C:14]2(C)[C:15]([O:17][C:18](=O)[CH:11]1[CH2:12][CH2:13]2)=[O:16].C([O-])(O)=[O:23].[Na+]>C(Cl)Cl.O>[O:5]=[C:4]1[CH:6]([NH:7][C:21]([C:10]2[CH:18]=[CH:11][CH:12]=[CH:13][C:14]=2[C:15]([OH:17])=[O:16])=[O:23])[CH2:1][CH2:2][S:3]1

Participants

6

Reactant 3

HCID 948341,8,8-Trimethyl-3-oxabicyclo[3.2.1]octane-2,4-dioneHCID 1107533622-59-1HCID 516892Sodium Bicarbonate

Product 1

HCID 3064724105441-18-7

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 6344DichloromethaneSolvent

Procedure

According to the same procedure, 10 g (65 mmol) of DL-homocysteine thiolactone hydrochloride, 11.52 g (63 mmol) of DL-camphoric anhydride and 5.46 g (65 mmol) of NaHCO3 in 42 ml of CH2Cl2 and 1 ml of H2O were reacted.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-eb299631771842fcb18a1c9a3c3eac7a
Source dataset
uspto-grants-1987_09
Patent number
US04690944

Reaction notes

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