Hydrochloric Acid → HCID 54193761, compound

HRID 2308933Notes

Reaction equation

HRID 2308933 reaction equation
Cl.[N+:2]([C:5]1[CH:17]=[CH:16][C:15]2[C:14]3[C:9](=[CH:10][C:11]([N+:18]([O-])=O)=[CH:12][CH:13]=3)[C:8](=[CH:21][CH:22]=[C:23]3[N:27]([CH3:28])[C:26]4[CH:29]=[CH:30][CH:31]=[CH:32][C:25]=4[O:24]3)[C:7]=2[CH:6]=1)([O-])=O.[Cl-].[Ca+2].[Cl-]>[Zn].C(O)C>[NH2:2][C:5]1[CH:17]=[CH:16][C:15]2[C:14]3[C:9](=[CH:10][C:11]([NH2:18])=[CH:12][CH:13]=3)[C:8](=[CH:21][CH:22]=[C:23]3[N:27]([CH3:28])[C:26]4[CH:29]=[CH:30][CH:31]=[CH:32][C:25]=4[O:24]3)[C:7]=2[CH:6]=1

Participants

6

Reactant 3

HCID 313Hydrochloric AcidHCID 5284359Calcium ChlorideHCID 54145196HCID 54145196, compound

Product 1

HCID 54193761HCID 54193761, compound

Reagents, catalysts & solvents 2

HCID 23994ZincCatalyst2×HCID 702EthanolSolvent

Procedure

Zinc dust in an amount of 40 g was added with 50 ml of 10% hydrochloric acid, and the resulted solution was lightly stirred and was then filtrated. The resulted matter was washed with ethanol, so that an active zinc dust was obtained. The resulted active zinc dusts were put into a flask of 300 ml capacity, and whereto 4.13 g (0.01 mole) of 2,7-dinitro-9-(3-methylbenzoxazolinylidene)ethylidenefluorene and 100 ml of ethanol were added, and further 2.5 ml of an aqueous solution of 0.56 g (0.005 mole) of calcium chloride were added thereto, and the resulted mixture was refluxed for 4 hours, and was then heat-filtrated. The mother liquid thereof was condensed, so that the objective matter was obtained. The yield thereof was 1.84 g (52%).

Workup

  1. filtrationwas then filtrated
  2. washThe resulted matter was washed with ethanol, so that an active zinc dust
  3. customwas obtained
  4. additionwere added
  5. temperaturethe resulted mixture was refluxed for 4 hours
  6. filtrationwas then heat-filtrated
  7. customcondensed
  8. customso that the objective matter was obtained
  9. customThe yield

Sources & evidence

ORD record
ord-84832ee7de0c420887fc12af3c43abca
Source dataset
uspto-grants-1987_09
Patent number
US04692393

Reaction notes

Loading…