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HRID2309218

反应详情

EQUATION

反应方程式

HRID 2309218 的结构方程式

REACTANTS

反应物

3
结构：CCO
HCID702

Ethanol

C2H6O

结构：[Cl-].[Cl-].[Mn+2]
HCID10313134

Manganese dichloride

Cl2Mn

结构：CC[C@@H](C(=O)[C@@H](C)[C@@H](O)[C@@H](C)[C@H]1O[C@@H](CC(=O)OO)[C@H](C)C[C@@H]1C)[C@H]1O[C@](C)([C@]2(O)O[C@](CC)([C@@H](O)CC)C[C@H]2C)C[C@@H]1C.[Na]
HCID86741790

未命名化合物

PRODUCTS

生成物

1
结构：CC[C@@H](C(=O)[C@@H](C)[C@@H](O)[C@@H](C)[C@H]1O[C@@H](CC(=O)OO)[C@H](C)C[C@@H]1C)[C@H]1O[C@](C)([C@]2(O)O[C@](CC)([C@@H](O)CC)C[C@H]2C)C[C@@H]1C.[Mn]
HCID86741789

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

A mixture of 6.5 g sodium lysocellin, 2.0 g manganese chloride and 100 ml of 90% ethanol was stirred and held at ambient temperature for 18 hours. Stirring was continued and water added slowly to precipitate a tacky semi-solid. Removal of the mother liquor by decantation and trituration of the residue with fresh water gave a filterable amorphous solid which was isolated and dried (6.4 g). The product had a melting point of 112.8° C. Analysis: Calculated % Mn (4.19); Found (3.75).

WORKUP

后处理

  1. stirringStirring
  2. customto precipitate a tacky semi-solid
  3. customRemoval of the mother liquor by decantation and trituration of the residue with fresh water
  4. customgave a filterable amorphous solid which
  5. customwas isolated
  6. customdried (6.4 g)