m-Chloroperbenzoic acid → HCID 14154362, compound

HRID 231163Notes

Reaction equation

HRID 231163 reaction equation
[C:1]([O:5][C:6]([N:8]1[C:12]2=[CH:13][S:14][CH:15]=[C:11]2[N:10]=[C:9]1[S:16][CH2:17][C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][N:19]=1)=[O:7])([CH3:4])([CH3:3])[CH3:2].C[O:26]C1C=CC(COC(N2C3=CSC=C3N=C2S(CC2C=CC(C)=CN=2)=O)=O)=CC=1.ClC1C=CC=C(C(OO)=O)C=1>C(Cl)Cl>[C:1]([O:5][C:6]([N:8]1[C:12]2=[CH:13][S:14][CH:15]=[C:11]2[N:10]=[C:9]1[S:16]([CH2:17][C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][N:19]=1)=[O:26])=[O:7])([CH3:4])([CH3:3])[CH3:2]

Participants

5

Reactant 3

HCID 70297m-Chloroperbenzoic acidHCID 14154328HCID 14154328, compoundHCID 20034625HCID 20034625, compound

Product 1

HCID 14154362HCID 14154362, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

1.1 g (3 mmol) of the title compound from Example 23 were dissolved in 50 ml of CH2Cl2, and 50 ml of the KH2PO4 /Na2HPO4 buffer solution from Example 22 were added. At 10° C. a total of 900 mg (4.5 mmol) of m-chloroperbenzoic acid in CH2Cl2 was added dropwise in portions until the precursor has been completely used up.

Sources & evidence

ORD record
ord-fa6af096bc5b4ea8b2b2bd9afe5eaac9
Source dataset
uspto-grants-1989_07
Patent number
US04845118

Reaction notes

Loading…