Bicarbonate Ion → Benzyl 4-formylbenzoate

HRID 2316236Notes

Reaction equation

HRID 2316236 reaction equation
[Br:20][CH2:21][c:22]1[cH:23][cH:24][cH:25][cH:26][cH:27]1.[C:14](=[O:15])([O-:16])[O-:17].[C:33](=[O:34])([OH:35])[O-:36].[CH3:12][OH:13].[CH:1](=[O:2])[c:3]1[cH:4][cH:5][c:6]([C:7](=[O:8])[OH:9])[cH:10][cH:11]1.[Cs+:18].[Cs+:19].[Na+:37].[O:28]=[CH:29][N:30]([CH3:31])[CH3:32].[OH2:38]>>[CH:1](=[O:2])[c:3]1[cH:4][cH:5][c:6]([C:7]([O:8][CH2:21][c:22]2[cH:23][cH:24][cH:25][cH:26][cH:27]2)=[O:9])[cH:10][cH:11]1

Participants

10

Reactant 9

HCID 769Bicarbonate IonHCID 887MethanolHCID 923Sodium ionHCID 962WaterHCID 6228DimethylformamideHCID 7498Benzyl BromideHCID 120884-Formylbenzoic acidHCID 19660Carbonate IonHCID 104967Cesium cation2×

Product 1

HCID 11528845Benzyl 4-formylbenzoate

Sources & evidence

ORD record
ord-4aa8b1bddd9946ee8c6bf3d2d0c27262
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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