Tetrahydrofuran → HCID 14297836, compound

HRID 231666Notes

Reaction equation

HRID 231666 reaction equation
CO[C:3]([C:6]1[CH:13]=[CH:12][C:9]([CH:10]=[O:11])=[CH:8][CH:7]=1)([CH3:5])[CH3:4].[CH2:14]1COCC1>>[CH3:14][O:11][CH2:10][CH:9]1[CH2:12][CH2:13][CH:6]([CH:3]([CH3:5])[CH3:4])[CH2:7][CH2:8]1

Participants

3

Reactant 2

HCID 8028TetrahydrofuranHCID 14121778116473-61-1

Product 1

HCID 14297836HCID 14297836, compound

Procedure

In an autoclave, 405 g (2.5 moles) of the 4-(1-methoxy-1-methylethyl)-benzaldehyde obtained according to A, in 200 ml of THF, were flushed several times with nitrogen and hydrogen in the presence of 1 g of ruthenium hydroxide and then hydrogenated at 150° C. and under a hydrogen pressure of 300 bar until the pressure remained constant.

Workup

  1. customwere flushed several times with nitrogen and hydrogen in the presence of 1 g of ruthenium hydroxide
  2. customhydrogenated at 150° C. and under a hydrogen

Sources & evidence

ORD record
ord-3a84274cd7ca4c40a859b34ff1a9f605
Source dataset
uspto-grants-1989_07
Patent number
US04847425

Reaction notes

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