HRID2319176

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8028

Tetrahydrofuran

C4H8O

HCID28486

Lithium ion

Li+

HCID568601

Ethyl 3-(trimethylsilyl)propiolate

C8H14O2Si

HCID3280088

未命名化合物

结构：N#Cc1ccc(F)c(Cc2cccc(-c3ccc(F)cc3F)n2)c1

HCID57700368

未命名化合物

PRODUCTS

生成物

结构：C[Si](C)(C)C#CC(=O)C(c1cccc(-c2ccc(F)cc2F)n1)c1cc(C#N)ccc1F

HCID57700369

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-cdc9983622a44dcdb0120f825f8d4a6a
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (10/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (10/10)

反应 SMILES

[CH2:46]1[O:47][CH2:48][CH2:49][CH2:50]1.[CH3:26][Si:27]([N-:28][Si:29]([CH3:30])([CH3:31])[CH3:32])([CH3:33])[CH3:34].[CH3:35][Si:36]([C:37]#[C:38][C:39](=[O:40])[O:41][CH2:42][CH3:43])([CH3:44])[CH3:45].[F:1][c:2]1[c:3](-[c:9]2[cH:10][cH:11][cH:12][c:13]([CH2:15][c:16]3[cH:17][c:18]([C:19]#[N:20])[cH:21][cH:22][c:23]3[F:24])[n:14]2)[cH:4][cH:5][c:6]([F:8])[cH:7]1.[Li+:25]>>[F:1][c:2]1[c:3](-[c:9]2[cH:10][cH:11][cH:12][c:13]([CH:15]([c:16]3[cH:17][c:18]([C:19]#[N:20])[cH:21][cH:22][c:23]3[F:24])[C:39]([C:38]#[C:37][Si:36]([CH3:35])([CH3:44])[CH3:45])=[O:40])[n:14]2)[cH:4][cH:5][c:6]([F:8])[cH:7]1