Acetate → 2-(2-Phenylethenyl)pyridin-4-amine

HRID 2319811Notes

Reaction equation

HRID 2319811 reaction equation
[Br:20][c:21]1[n:22][cH:23][cH:24][c:25]([NH2:27])[cH:26]1.[C:54]([O-:55])(=[O:56])[CH3:57].[C:59]([O-:60])(=[O:61])[CH3:62].[CH2:28]([Sn:29]([CH2:30][CH2:31][CH2:32][CH3:41])([CH:33]=[CH:34][c:35]1[cH:36][cH:37][cH:38][cH:39][cH:40]1)[CH2:42][CH2:43][CH2:44][CH3:45])[CH2:46][CH2:47][CH3:48].[O:49]=[CH:50][N:51]([CH3:52])[CH3:53].[Pd+2:58].[c:1]1([P:2]([c:3]2[cH:4][cH:5][cH:6][cH:7][cH:8]2)[c:9]2[cH:10][cH:11][cH:12][cH:13][cH:14]2)[cH:15][cH:16][cH:17][cH:18][cH:19]1>>[c:21]1([CH:33]=[CH:34][c:35]2[cH:36][cH:37][cH:38][cH:39][cH:40]2)[n:22][cH:23][cH:24][c:25]([NH2:27])[cH:26]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 6228DimethylformamideHCID 11776TriphenylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 3464554-Amino-2-bromopyridineHCID 4372073HCID 4372073, compound

Product 1

HCID 695920282-(2-Phenylethenyl)pyridin-4-amine

Sources & evidence

ORD record
ord-0392cca0eabc473bab14692e901518aa
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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