HRID2320208

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID3283

Diethyl Ether

C4H10O

HCID8028

Tetrahydrofuran

C4H8O

HCID11776

Triphenylphosphine

C18H15P

4 次

HCID23938

Palladium

结构：CC(C)(C)[Si](OCc1cccc(Br)n1)(c1ccccc1)c1ccccc1

HCID23370237

未命名化合物

HCID178505839

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)[Si](OCc1cccc(-c2ccc(F)cc2)n1)(c1ccccc1)c1ccccc1

HCID23370183

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-71b46eb99a674941aa6f218bee314e0f
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (10/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (10/10)

反应 SMILES

[Br-:27].[Br:1][c:2]1[n:3][c:4]([CH2:8][O:9][Si:10]([c:11]2[cH:12][cH:13][cH:14][cH:15][cH:16]2)([c:17]2[cH:18][cH:19][cH:20][cH:21][cH:22]2)[C:23]([CH3:24])([CH3:25])[CH3:26])[cH:5][cH:6][cH:7]1.[CH2:41]1[O:42][CH2:43][CH2:44][CH2:45]1.[CH3:36][CH2:37][O:38][CH2:39][CH3:40].[F:28][c:29]1[cH:30][cH:31][c:32]([Mg+:35])[cH:33][cH:34]1.[Pd:46].[c:104]1([P:105]([c:106]2[cH:107][cH:108][cH:109][cH:110][cH:111]2)[c:112]2[cH:113][cH:114][cH:115][cH:116][cH:117]2)[cH:118][cH:119][cH:120][cH:121][cH:122]1.[c:47]1([P:48]([c:49]2[cH:50][cH:51][cH:52][cH:53][cH:54]2)[c:55]2[cH:56][cH:57][cH:58][cH:59][cH:60]2)[cH:61][cH:62][cH:63][cH:64][cH:65]1.[c:66]1([P:67]([c:68]2[cH:69][cH:70][cH:71][cH:72][cH:73]2)[c:74]2[cH:75][cH:76][cH:77][cH:78][cH:79]2)[cH:80][cH:81][cH:82][cH:83][cH:84]1.[c:85]1([P:86]([c:87]2[cH:88][cH:89][cH:90][cH:91][cH:92]2)[c:93]2[cH:94][cH:95][cH:96][cH:97][cH:98]2)[cH:99][cH:100][cH:101][cH:102][cH:103]1>>[c:2]1(-[c:32]2[cH:31][cH:30][c:29]([F:28])[cH:34][cH:33]2)[n:3][c:4]([CH2:8][O:9][Si:10]([c:11]2[cH:12][cH:13][cH:14][cH:15][cH:16]2)([c:17]2[cH:18][cH:19][cH:20][cH:21][cH:22]2)[C:23]([CH3:24])([CH3:25])[CH3:26])[cH:5][cH:6][cH:7]1