Potassium Cation → 3-Chloro-10,11-dihydro-5H-benzo(d)naphtho(2,3-b)pyran-8(9H)-one

HRID 2332500Notes

Reaction equation

HRID 2332500 reaction equation
[Br:36][c:37]1[c:38]([CH2:39][O:40][c:41]2[cH:42][cH:43][c:44]3[c:49]([cH:50]2)[C:48](=[O:51])[CH2:47][CH2:46][CH2:45]3)[cH:52][c:53]([Cl:56])[cH:54][cH:55]1.[C:30](=[O:31])([O-:32])[O-:33].[CH3:23][C:24]([C:25](=[O:26])[OH:27])([CH3:28])[CH3:29].[CH3:57][C:58]([N:59]([CH3:60])[CH3:61])=[O:62].[F:1][c:2]1[cH:3][cH:4][c:5]([P:6]([c:7]2[cH:8][cH:9][c:10]([F:11])[cH:12][cH:13]2)[c:14]2[cH:15][cH:16][c:17]([F:18])[cH:19][cH:20]2)[cH:21][cH:22]1.[K+:34].[K+:35]>>[c:37]12[c:38]([cH:52][c:53]([Cl:56])[cH:54][cH:55]1)[CH2:39][O:40][c:41]1[c:42]-2[cH:43][c:44]2[c:49]([cH:50]1)[C:48](=[O:51])[CH2:47][CH2:46][CH2:45]2

Participants

7

Reactant 6

HCID 813Potassium Cation2×HCID 6417Pivalic acidHCID 19660Carbonate IonHCID 31374DimethylacetamideHCID 140387Tris(4-fluorophenyl)phosphineHCID 696728137-((2-Bromo-5-chlorophenyl)methoxy)-1,2,3,4-tetrahydronaphthalen-1-one

Product 1

HCID 696733663-Chloro-10,11-dihydro-5H-benzo(d)naphtho(2,3-b)pyran-8(9H)-one

Sources & evidence

ORD record
ord-07bee4e541cc4338ba9d58cf07422c8c
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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