1,4-Dihydroxy-2,2,6,6-tetramethylpiperidine → 2,4,8,10-Tetra-tert-butyl-6-[1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yloxy]-12-methyl-12H-dibenzo[d,g][1,3,2]-dioxaphosphocin

HRID 2346241Notes

Reaction equation

HRID 2346241 reaction equation
[CH3:49][CH2:50][N:51]([CH2:52][CH3:53])[CH2:54][CH3:55].[CH:5]([CH3:6])([c:7]1[c:8]([OH:21])[c:9]([C:17]([CH3:18])([CH3:19])[CH3:20])[cH:10][c:11]([C:13]([CH3:14])([CH3:15])[CH3:16])[cH:12]1)[c:22]1[c:23]([OH:36])[c:24]([C:32]([CH3:33])([CH3:34])[CH3:35])[cH:25][c:26]([C:28]([CH3:29])([CH3:30])[CH3:31])[cH:27]1.[OH:37][N:38]1[C:39]([CH3:47])([CH3:48])[CH2:40][CH:41]([OH:46])[CH2:42][C:43]1([CH3:44])[CH3:45].[P:1]([Cl:2])([Cl:3])[Cl:4]>>[P:1]1([O:46][CH:41]2[CH2:40][C:39]([CH3:47])([CH3:48])[N:38]([OH:37])[C:43]([CH3:44])([CH3:45])[CH2:42]2)[O:21][c:8]2[c:7]([cH:12][c:11]([C:13]([CH3:14])([CH3:15])[CH3:16])[cH:10][c:9]2[C:17]([CH3:18])([CH3:19])[CH3:20])[CH:5]([CH3:6])[c:22]2[c:23]([c:24]([C:32]([CH3:33])([CH3:34])[CH3:35])[cH:25][c:26]([C:28]([CH3:29])([CH3:30])[CH3:31])[cH:27]2)[O:36]1

Participants

5

Reactant 4

HCID 53951,4-Dihydroxy-2,2,6,6-tetramethylpiperidineHCID 8471TriethylamineHCID 24387Phosphorus trichlorideHCID 1188992,2'-Ethylidenebis(4,6-di-tert-butylphenol)

Product 1

HCID 212737242,4,8,10-Tetra-tert-butyl-6-[1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yloxy]-12-methyl-12H-dibenzo[d,g][1,3,2]-dioxaphosphocin

Sources & evidence

ORD record
ord-e3a6a241c2f343119f5b2965d6dbe75c
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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