Nitrate → HCID 70401095, compound

HRID 2352624Notes

Reaction equation

HRID 2352624 reaction equation
[N+:1]([O-:4])([O-:3])=[O:2].[N+]([O-])(O)=O.[C:9]([O:12][CH2:13][CH3:14])(=[O:11])C.CCOCC>C(OCC)(=O)C>[N+:1]([O-:4])([OH:3])=[O:2].[O:11]1[CH2:14][CH2:13][O:12][CH2:9]1

Participants

5

Reactant 3

HCID 943NitrateHCID 3283Diethyl EtherHCID 131715915HCID 131715915, compound

Product 1

HCID 70401095HCID 70401095, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

analysis: C28H23Cl2N3O4 (MW 536.43) calc. C 62.69, H 4.32, N 7.83; found C 62.4, H 4.4, N 7.6. Nitrate formation: 1.93 g (3.6 mmol) of base were dissolved in 15 ml of ethyl acetate, and 3.6 ml of 1M HNO3 /ethyl acetate were added with stirring. Ether was subsequently added until no further precipitate was produced, and the precipitate was filtered off under suction. 2.05 g (yield of nitrate, 95.3% of theory) of cis-2-(2,4-dichlorophenyl)-2-(imidazol-1-ylmethyl)-4-[4-(benzoxazol-2-yl)benzyl)oxymethyl]-1,3-dioxolane nitrate were obtained; melting point 121°-2° C.,

Workup

  1. customwas produced
  2. filtrationthe precipitate was filtered off under suction

Sources & evidence

ORD record
ord-869a623af4db439b91173ecc828851bb
Source dataset
uspto-grants-1989_10
Patent number
US04877878

Reaction notes

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