Azobisisobutyronitrile → HCID 19843642, compound

HRID 2352673Notes

Reaction equation

HRID 2352673 reaction equation
[SH:1][CH2:2][CH:3]([OH:6])[CH2:4][OH:5].[CH3:7][C:8]([CH3:12])([CH3:11])[CH:9]=[CH2:10].N(C(C)(C)C#N)=NC(C)(C)C#N>CCCCCC>[CH3:7][C:8]([CH3:12])([CH3:11])[CH2:9][CH2:10][S:1][CH2:2][CH:3]([OH:6])[CH2:4][OH:5]

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 7291ThioglycerolHCID 112103,3-Dimethyl-1-butene

Product 1

HCID 19843642HCID 19843642, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

A mixture of 3-mercapto-1,2-propanediol (10.8 g), 3,3-dimethyl-1-butene (9.6 g) and 2,2'-azobis(2-methylpropionitrile) (0.5 g) is heated under reflux with vigorous stirring for 20 hours, then is diluted with hexane, extracted with water and stripped to give 3-(3,3-dimethylbutylthio)-1,2propanediol.

Workup

  1. temperatureis heated
  2. temperatureunder reflux
  3. extractionextracted with water

Sources & evidence

ORD record
ord-66b722dbf0fe41a4b544c989744b6fb4
Source dataset
uspto-grants-1989_10
Patent number
US04877899

Reaction notes

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