Methanol → HCID 54335577, compound

HRID 2352675Notes

Reaction equation

HRID 2352675 reaction equation
[CH2:1]([S:7][CH:8]=[CH:9][CH2:10]Cl)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].C(N(C(C)C)CC)(C)C.[CH3:21][OH:22]>CCCCCC>[CH3:21][O:22][CH2:10][CH:9]=[CH:8][S:7][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Participants

5

Reactant 3

HCID 887MethanolHCID 81531DiisopropylethylamineHCID 54172172HCID 54172172, compound

Product 1

HCID 54335577HCID 54335577, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

3-Hexylthio-2-propenyl chloride is added to a solution of diisopropyl ethyl amine (3.68 g, 28.5 mmol) in 20 ml of methanol. The mixture is stirred overnight at RT. It is then diluted with hexane, washed with water and with brine and is stripped. The crude product is purified by prep. TLC to give 3-methoxy-1-hexylthio-1-propene.

Workup

  1. washwashed with water and with brine
  2. customThe crude product is purified by prep

Sources & evidence

ORD record
ord-3f5b6b6e640848808e565dc80061b09b
Source dataset
uspto-grants-1989_10
Patent number
US04877899

Reaction notes

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