Pivalic acid → HCID 86620826, compound

HRID 2353205Notes

Reaction equation

[C:1](=[O:13])([S:11][CH3:12])[O:2][CH:3]([O:5][C:6](=[O:10])[CH:7]([CH3:9])[CH3:8])C.Cl[C:15](OCCl)=O.C(O)(=O)C(C)(C)C>>[C:1](=[O:13])([S:11][CH3:12])[O:2][CH2:3][O:5][C:6](=[O:10])[C:7]([CH3:15])([CH3:9])[CH3:8]

Participants

Reactant 3

HCID 6417Pivalic acid

HCID 62754Chloromethyl chloroformate

HCID 577926891-[[(Methylthio)carbonyl]oxy]ethyl 2-methylpropanoate

Product 1

HCID 86620826HCID 86620826, compound

Procedure

Following the procedures for synthesizing O-(1-isobutanoyloxyethyl) S-methyl thiocarbonate (2) and replacing 1-chloroethyl chloroformate with chloromethyl chloroformate in Step A and replacing isobutyric acid with pivalic acid in Step B affords O-(pivaloyloxymethyl) S-methyl thiocarbonate (9) as an oil.

Sources & evidence

ORD record: ord-d34a8b9174804d0a85729bb534868830
Source dataset: uspto-grants-2010_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07749985B2

Reaction notes

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