Benzoic Acid → HCID 86241954, compound

HRID 2353207Notes

Reaction equation

[C:1](=[O:13])([S:11][CH3:12])[O:2][CH:3]([O:5][C:6](=[O:10])[CH:7]([CH3:9])[CH3:8])C.ClC(OCCl)=O.[C:20](O)(=O)[C:21]1C=CC=C[CH:22]=1>>[C:1](=[O:13])([S:11][CH3:12])[O:2][CH2:3][O:5][C:6](=[O:10])[C:7]1[CH:9]=[CH:22][CH:21]=[CH:20][CH:8]=1

Participants

Reactant 3

HCID 243Benzoic Acid

HCID 62754Chloromethyl chloroformate

HCID 577926891-[[(Methylthio)carbonyl]oxy]ethyl 2-methylpropanoate

Product 1

HCID 86241954HCID 86241954, compound

Procedure

Following the procedures for synthesizing O-(1-isobutanoyloxyethyl) S-methyl thiocarbonate (2) and replacing 1-chloroethyl chloroformate with chloromethyl chloroformate in Step A and replacing isobutyric acid with benzoic acid in Step B affords O-(benzoyloxymethyl) S-methyl thiocarbonate (213) as an oil.

Sources & evidence

ORD record: ord-7d45e08dc2ae447284e20c3307b9bd18
Source dataset: uspto-grants-2010_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07749985B2

Reaction notes

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