Water → HCID 57448069, compound

HRID 2358122Notes

Reaction equation

HRID 2358122 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([S:8][C:9]([F:12])([F:11])[F:10])[C:3]=1[F:13].C(Cl)(Cl)(Cl)Cl.C(#N)C.I([O-])(=O)(=O)=[O:23].[Na+].[OH2:28]>[Ru](Cl)(Cl)Cl>[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([S:8]([C:9]([F:11])([F:12])[F:10])(=[O:23])=[O:28])[C:3]=1[F:13]

Participants

7

Reactant 5

HCID 962WaterHCID 5943Carbon TetrachlorideHCID 6342AcetonitrileHCID 23667635Sodium periodateHCID 57448068HCID 57448068, compound

Product 1

HCID 57448069HCID 57448069, compound

Reagents, catalysts & solvents 1

HCID 61850Ruthenium trichlorideCatalyst

Procedure

Preparation according to preparation 4: 1-bromo-2-fluoro-3-[(trifluoromethyl)thio]benzene (0.37 g), carbon tetrachloride (4 ml), acetonitrile (4 ml), water (8 ml), sodium periodate (0.86 g), ruthenium trichloride (1 mg). Yield: 0.3 g. MS m/z (rel. intensity, 70 eV) 308 (M+, 18), 306 (M+, 19), 239 (57), 173 (60), 94 (bp).

Workup

  1. customPreparation
  2. customaccording to preparation 4

Sources & evidence

ORD record
ord-0bd85fb939b4404d816b2e96ead9eec3
Source dataset
uspto-grants-2010_07
Patent number
US07763639B2

Reaction notes

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