Toluene → HCID 86600217, compound

HRID 2367849Notes

Reaction equation

HRID 2367849 reaction equation
N[CH2:2][CH2:3][CH2:4][Si:5]([O:10][CH3:11])([O:8][CH3:9])[O:6][CH3:7].C1(C)C=CC=CC=1.[C:19](Cl)(=[O:21])[CH3:20].C([N:25](CC)CC)C>>[CH3:7][O:6][Si:5]([CH2:4][CH2:3][CH2:2][CH2:20][C:19]([NH2:25])=[O:21])([O:10][CH3:11])[O:8][CH3:9]

Participants

5

Reactant 4

HCID 1140TolueneHCID 6367Acetyl chlorideHCID 8471TriethylamineHCID 83756Aminopropyltrimethoxysilane

Product 1

HCID 86600217HCID 86600217, compound

Procedure

A three-neck round-bottomed flask, equipped with a mechanical stirrer, a refluxing condenser and a dropping funnel, was charged with 3-aminopropyltrimethoxysilane (18 gram, Gelest Inc.), toluene (40 mL, Aldrich) and triethylamine (13 gram, Aldrich). Stirring was started, and an appropriate acyl chloride such as acetyl chloride (18 mL, Aldrich) was added dropwise to the flask. The mixture was stirred at room temperature under an argon atmosphere for 16 hours.

Workup

  1. customA three-neck round-bottomed flask, equipped with a mechanical stirrer, a refluxing condenser and a dropping funnel
  2. stirringThe mixture was stirred at room temperature under an argon atmosphere for 16 hours

Sources & evidence

ORD record
ord-8a054f2e75814adfa1cc3ccec0d8df9f
Source dataset
uspto-grants-2014_04
Patent number
US08702988B2

Reaction notes

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