Water → Cerous carbonate
Reaction equation
[N+]([O-])([O-])=[O:2].[Ce+3:5].[N+]([O-])([O-])=[O:7].[N+]([O-])([O-])=[O:11].N[C:15](N)=[O:16].[OH2:18]>>[C:15](=[O:16])([O-:11])[O-:18].[Ce+3:5].[C:15](=[O:16])([O-:7])[O-:18].[C:15](=[O:16])([O-:2])[O-:18].[Ce+3:5]Participants
4
Conditions
- Temperature
- 140 °C
Procedure
43.4 kg of cerium nitrate and 18 kg of urea were mixed at atmospheric pressure (1 atm) and room temperature, and then reacted for 16 hours in a reactor that was heated to 140° C. Subsequently, the resultant was slowly cooled and diluted with water, leading to termination of the reaction, and then dried under vacuum at 80° C. for 24 hours to obtain a cerium carbonate-based compound.
Workup
- customreacted for 16 hours in a reactor that
- temperatureSubsequently, the resultant was slowly cooled
- customleading to termination of the reaction
- customdried under vacuum at 80° C. for 24 hours
Sources & evidence
- ORD record
- ord-90d216a410ec478d953f0e0bdb2619d2
- Source dataset
- uspto-grants-2014_04
- Patent number
- US08703085B2
Reaction notes
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