Sodium Bicarbonate → HCID 20304561, compound

HRID 236951Notes

Reaction equation

HRID 236951 reaction equation
[CH2:1]([C:3]1[C:12]2[O:13][C:14]([C:18]([O:20]C)=[O:19])=[CH:15][C:16](=[O:17])[C:11]=2[CH:10]=[C:9]2[C:4]=1[CH2:5][CH2:6][CH2:7][CH2:8]2)[CH3:2].C(=O)(O)[O-].[Na+]>O>[CH2:1]([C:3]1[C:12]2[O:13][C:14]([C:18]([OH:20])=[O:19])=[CH:15][C:16](=[O:17])[C:11]=2[CH:10]=[C:9]2[C:4]=1[CH2:5][CH2:6][CH2:7][CH2:8]2)[CH3:2]

Participants

4

Reactant 2

HCID 516892Sodium BicarbonateHCID 20304522HCID 20304522, compound

Product 1

HCID 20304561HCID 20304561, compoundYield 84.1%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of the product of step (b) (3.0 g) and sodium bicarbonate (3.0 g) in water (100 ml) was heated at reflux for 3 hours. The solution was cooled and acidified and the resulting white solid was filtered and dried to give the title compound 2.4 g (84%), mp 269°-271°.

Workup

  1. temperaturewas heated
  2. temperatureat reflux for 3 hours
  3. temperatureThe solution was cooled
  4. filtrationthe resulting white solid was filtered
  5. customdried

Sources & evidence

ORD record
ord-a2ec43410cb94413a17eb3f9e7321254
Source dataset
uspto-grants-1979_06
Patent number
US04159273

Reaction notes

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