Ethanol → HCID 67903179, compound

HRID 2371537Notes

Reaction equation

HRID 2371537 reaction equation
[CH2:1]([N:3]([CH2:6][CH2:7][CH2:8][CH2:9][C:10]1[CH:15]=[CH:14][C:13]([CH2:16][CH2:17][CH2:18][CH2:19][N:20]([CH2:23][CH3:24])[CH2:21][CH3:22])=[CH:12][CH:11]=1)[CH2:4][CH3:5])[CH3:2].[CH2:25]([I:27])[CH3:26].[CH2:28](O)[CH3:29]>>[I-:27].[I-:27].[CH2:23]([N+:20]([CH2:19][CH2:18][CH2:17][CH2:16][C:13]1[CH:12]=[CH:11][C:10]([CH2:9][CH2:8][CH2:7][CH2:6][N+:3]([CH2:25][CH3:26])([CH2:4][CH3:5])[CH2:1][CH3:2])=[CH:15][CH:14]=1)([CH2:28][CH3:29])[CH2:21][CH3:22])[CH3:24]

Participants

4

Reactant 3

HCID 702EthanolHCID 6340IodoethaneHCID 19907473HCID 19907473, compound

Product 1

HCID 67903179HCID 67903179, compound

Procedure

First, 0.56 g of 1,4-bis(diethylaminobutyl)benzene and 2.1 g of ethyl iodide were dissolved in 7 ml of absolute ethanol, and the mixture was refluxed for 4 hours. After removing the solvent under a reduced pressure and adding acetone and a small amount of ethanol, the mixture was stirred at a room temperature for 30 minutes. The resulting crystal was filtered, washed with acetone, and dried under a reduced pressure to obtain 0.335 g of the title compound as a pale yellow crystal.

Workup

  1. temperaturethe mixture was refluxed for 4 hours
  2. customAfter removing the solvent under a reduced pressure
  3. additionadding acetone
  4. filtrationThe resulting crystal was filtered
  5. washwashed with acetone
  6. customdried under a reduced pressure

Sources & evidence

ORD record
ord-322fd28f4c134a09baaa173e64e8be6b
Source dataset
uspto-grants-1992_03
Patent number
US05093370

Reaction notes

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