Ethanol → HCID 19907475, compound

HRID 2371550Notes

Reaction equation

HRID 2371550 reaction equation
[CH2:1]([N:3]([CH2:29][CH3:30])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][C:11]1[CH:16]=[CH:15][C:14]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][N:24]([CH2:27][CH3:28])[CH2:25][CH3:26])=[CH:13][CH:12]=1)[CH3:2].[CH2:31]([I:33])[CH3:32].[CH2:34](O)[CH3:35]>>[I-:33].[I-:33].[CH2:27]([N+:24]([CH2:31][CH3:32])([CH2:25][CH3:26])[CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][C:14]1[CH:13]=[CH:12][C:11]([CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][N+:3]([CH2:34][CH3:35])([CH2:1][CH3:2])[CH2:29][CH3:30])=[CH:16][CH:15]=1)[CH3:28]

Participants

4

Reactant 3

HCID 702EthanolHCID 6340IodoethaneHCID 19907397HCID 19907397, compound

Product 1

HCID 19907475HCID 19907475, compound

Procedure

To solution of 97 mg of 1,4-bis(7-diethylaminoheptyl)benzene in 1 ml of absolute ethanol, was added 187 μl of ethyl iodide, and the mixture was refluxed for 3 hours and evaporated under a reduced pressure. After adding acetone, the mixture was concentrated and allowed to stand in a freezer for a week to obtain 152 mg of the title compound as a pale brown crystal.

Workup

  1. temperaturethe mixture was refluxed for 3 hours
  2. customevaporated under a reduced pressure
  3. additionAfter adding acetone
  4. concentrationthe mixture was concentrated
  5. waitto stand in a freezer for a week

Sources & evidence

ORD record
ord-8ea9848004e54a2a998631496a021e58
Source dataset
uspto-grants-1992_03
Patent number
US05093370

Reaction notes

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