Ammonium Acetate → HCID 14745922, compound

HRID 2372938Notes

Reaction equation

HRID 2372938 reaction equation
[Cl:1]/[C:2](/[C:11]([O:13][CH2:14][CH2:15][CH3:16])=[O:12])=[C:3](\Cl)/[C:4]([O:6][CH2:7][CH2:8][CH3:9])=[O:5].C([O-])(=O)C.[NH4+:21]>CN(C)C=O>[NH2:21]/[C:3](/[C:4]([O:6][CH2:7][CH2:8][CH3:9])=[O:5])=[C:2](\[Cl:1])/[C:11]([O:13][CH2:14][CH2:15][CH3:16])=[O:12]

Participants

4

Reactant 2

HCID 517165Ammonium AcetateHCID 19902721HCID 19902721, compound

Product 1

HCID 14745922HCID 14745922, compoundYield 96.5%

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

26.9 g (0.1 mol) of dipropyl dichloromaleate, 19.27 g (0.25 mol) of ammonium acetate and 40 ml of dimethylformamide were reacted under the same conditions as described in Example 1. 24.1 g (87.4% yield) of dipropyl aminochloromaleate were obtained as a reddish, viscous liquid (purity according to GC analysis 90.5%)

Sources & evidence

ORD record
ord-d3c00851bbf942ea9f3db65946ded04c
Source dataset
uspto-grants-1992_03
Patent number
US05101067

Reaction notes

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