Ammonium Acetate → HCID 14745923, compound

HRID 2372939Notes

Reaction equation

HRID 2372939 reaction equation
[Cl:1]/[C:2](/[C:12]([O:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:13])=[C:3](\Cl)/[C:4]([O:6][CH2:7][CH2:8][CH2:9][CH3:10])=[O:5].C([O-])(=O)C.[NH4+:23]>CN(C)C=O>[NH2:23]/[C:3](/[C:4]([O:6][CH2:7][CH2:8][CH2:9][CH3:10])=[O:5])=[C:2](\[Cl:1])/[C:12]([O:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:13]

Participants

4

Reactant 2

HCID 517165Ammonium AcetateHCID 19902720HCID 19902720, compound

Product 1

HCID 14745923HCID 14745923, compoundYield 99.2%

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

29.7 g (0.1 mol) of dibutyl dichloromaleate, 19.27 g (0.25 mol) of ammonium acetate and 40 ml of dimethylformamide were reacted under the same conditions as described in Example 1. 27.55 g (88.7% yield) of dibutyl aminochloromaleate were obtained as a reddish, viscous liquid (purity according to GC analysis 90%).

Sources & evidence

ORD record
ord-cac8ce742d1744ec89db403db1eb4d84
Source dataset
uspto-grants-1992_03
Patent number
US05101067

Reaction notes

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