1-Naphthaldehyde → HCID 19902783, compound

HRID 2373096Notes

Reaction equation

HRID 2373096 reaction equation
[CH3:1][C:2]([C:4]1[C:13]2[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=2)[CH:7]=[CH:6][CH:5]=1)=[O:3].[C:14]1([CH:24]=O)[C:23]2[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:17]=[CH:16][CH:15]=1.[OH-:26].[Na+]>C(O)C>[C:14]1([CH2:24][C:1](=[O:26])[CH:2]([C:4]2[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[CH:7]=[CH:6][CH:5]=2)[OH:3])[C:23]2[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:17]=[CH:16][CH:15]=1

Participants

5

Reactant 3

HCID 61951-NaphthaldehydeHCID 136631-AcetylnaphthaleneHCID 14798Sodium Hydroxide

Product 1

HCID 19902783HCID 19902783, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

1-Acetonaphtone is reacted with 1-naphtoaldehyde and sodium hydroxide in ethanol to produce 1,3-dinaphthyl-3-hydroxypropanone. The resulting compound is reacted with KHSO4 to obtain 1,3-dinaphthyl-3-propene-1-on. The resulting compound is reacted with hydrazine and potassium hydroxide in triethylene glycol to produce 1,3-dinaphthylpropane. 1,3-Dinaphthylpropane is reacted with fuming nitric acid and acetic acid anhydride to produce 1,3-dinitronaphthylpropane.

Sources & evidence

ORD record
ord-50916772d7a8457ab9e81ad2d578e2e2
Source dataset
uspto-grants-1992_03
Patent number
US05101411

Reaction notes

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