Azobisisobutyronitrile → HCID 86609791, compound

HRID 2374112Notes

Reaction equation

HRID 2374112 reaction equation
[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[F:10][C:11]([F:18])([F:17])[C:12](=[CH2:16])[C:13]([OH:15])=[O:14].[C:19]([O:24][CH2:25][C:26]([F:34])([F:33])[CH:27]([F:32])[C:28]([F:31])([F:30])[F:29])(=[O:23])[C:20]([CH3:22])=[CH2:21].CC(N=NC(C#N)(C)C)(C#N)C>CC(C)=O>[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[F:10][C:11]([F:18])([F:17])[C:12](=[CH2:16])[C:13]([OH:15])=[O:14].[C:19]([O:24][CH2:25][C:26]([F:33])([F:34])[CH:27]([F:32])[C:28]([F:30])([F:31])[F:29])(=[O:23])[C:20]([CH3:22])=[CH2:21]

Participants

6

Reactant 4

HCID 6547AzobisisobutyronitrileHCID 15458tert-Butyl acrylateHCID 5497721H,1H,3H-Perfluorobutyl 2-methylacrylateHCID 5876942-(Trifluoromethyl)acrylic acid

Product 1

HCID 86609791HCID 86609791, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

5 g of t-butylacrylate, 2.5 g of 2-(trifluoromethyl)acrylic acid, 2.5 g of 2,2,3,4,4,4-hexafluorobutyl methacrylate and 0.2 g of AIBN were dissolved in 50 g of acetone. The monomers were polymerized at 67° C. for 6 hours. After completion of the polymerization, the polymerization product was precipitated in water, filtered, and dried in a vacuum to give poly(t-butylacrylate-2-(trifluoromethyl)acrylic acid-2,2,3,4,4,4-hexafluorobutyl methacrylate) (yield: 75%) of Formula 3, below:

Workup

  1. customThe monomers were polymerized at 67° C. for 6 hours
  2. customAfter completion of the polymerization
  3. customthe polymerization product was precipitated in water
  4. filtrationfiltered
  5. customdried in a vacuum

Sources & evidence

ORD record
ord-dcc1c8070e17481484919492943cc6a6
Source dataset
uspto-grants-2008_12
Patent number
US07462439B2

Reaction notes

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