Hydrochloric Acid → N,N-Diethyl-P-phenylenediamine dihydrochloride

HRID 2382613노트

반응식

HRID 2382613 반응식
[CH2:1]([N:3]([CH2:11][CH3:12])[C:4]1[CH:9]=[CH:8][C:7]([NH2:10])=[CH:6][CH:5]=1)[CH3:2].[ClH:13]>C(OCC)C>[ClH:13].[ClH:13].[CH2:11]([N:3]([CH2:1][CH3:2])[C:4]1[CH:9]=[CH:8][C:7]([NH2:10])=[CH:6][CH:5]=1)[CH3:12]

참가 물질

4

반응물 2

HCID 313Hydrochloric AcidHCID 7120N,N-Diethyl-p-phenylenediamine

생성물 1

HCID 19799983N,N-Diethyl-P-phenylenediamine dihydrochloride수율 100%

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

N,N-diethyl-p-phenylenediamine (5 g, 30.4 mmol) was dissolved in diethyl ether (25 cm3) and hydrochloric acid (6 cm3, 10 M) was added and the mixture was concentrated to give the title compound (7.22 g, 100%) as a red/brown solid. δH (250 MHz; D2O): 7.68 (4H, m, ArH), 3.69 (4H, q, 7.32, NCH2), 1.11 (6H, t, 7.32, CH3); δC (62.9 MHz; D2O): 12.1 (CH3), 56.4 (NCH2), 126.8 (ArC), 127.6 (ArC), 135.5 (ArC), 139.1 (ArC).

후처리

  1. concentrationthe mixture was concentrated

출처 및 근거

ORD 기록
ord-8267668ac6c0450684fa09864b622c26
출처 데이터셋
uspto-grants-2012_09
특허 번호
US08263589B2

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