2-Hydroxyethyl acrylate → HCID 14298189, compound

HRID 2384309Notes

Reaction equation

HRID 2384309 reaction equation
[C:1]([O:6][CH2:7][CH2:8][N:9]=[C:10]=[O:11])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:12]([O:16][CH2:17][CH2:18][OH:19])(=[O:15])[CH:13]=[CH2:14]>C([O-])(=O)CCCCCCCCCCC.C([O-])(=O)CCCCCCCCCCC.C([Sn+2]CCCC)CCC>[CH3:3][C:2](=[CH2:4])[C:1]([O:6][CH2:7][CH2:8][NH:9][C:10]([O:19][CH2:18][CH2:17][O:16][C:12](=[O:15])[CH:13]=[CH2:14])=[O:11])=[O:5]

Participants

4

Reactant 2

HCID 131652-Hydroxyethyl acrylateHCID 354092-Isocyanatoethyl methacrylate

Product 1

HCID 14298189HCID 14298189, compound

Reagents, catalysts & solvents 1

HCID 9809426Di-n-butyldilauryltinCatalyst

Procedure

In a 4 ounce glass jar were mixed 2-isocyanatoethyl methacrylate (15.5 g, 0.10 mol, available from Aldrich), 2-hydroxyethyl acrylate (11.6 g, 0.10 mol, available from Aldrich), and one drop of di-n-butyltin dilaurate (available from Alfa Aesar) to cause a slight exotherm. The jar was cooled briefly in an ice bath, and then left at room temperature overnight. NMR and IR spectral analyses confirmed the structure of the product.

Workup

  1. temperatureThe jar was cooled briefly in an ice bath

Sources & evidence

ORD record
ord-b9af0686519e453bb6730a419e9e96ae
Source dataset
uspto-grants-2012_09
Patent number
US08263711B2

Reaction notes

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