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HRID238477

反应详情

EQUATION

反应方程式

HRID 238477 的结构方程式

REACTANTS

反应物

2
结构：O=C([O-])[O-].[K+].[K+]
HCID11430

Potassium Carbonate

CK2O3

结构：CC(C)(Br)C(=O)Nc1cc([N+](=O)[O-])ccc1O
HCID10566329

未命名化合物

PRODUCTS

生成物

1
结构：CC1(C)Oc2ccc([N+](=O)[O-])cc2NC1=O
HCID10656631

2,2-DIMETHYL-6-NITRO-2H-BENZO[B][1,4]OXAZIN-3(4H)-ONE

C10H10N2O4

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

CONDITIONS

反应条件

温度
50 °C

PROCEDURE

实验过程

2-Bromo-N-(2-hydroxy-5-nitro-phenyl)-2-methyl-propionamide was mixed with K2CO3 in 20 mL of DMF and stirred overnight at 50° C. The reaction mixture was poured into ice water. The precipitate was collected by filtration and washed with H2O. The crude compound was recrystallized from EtOH.

WORKUP

后处理

  1. filtrationThe precipitate was collected by filtration
  2. washwashed with H2O
  3. customThe crude compound was recrystallized from EtOH