Phenolate Sodium → HCID 86654805, compound

HRID 239197Notes

Reaction equation

HRID 239197 reaction equation
[CH2:1]([N+:5]([CH2:14][CH2:15][CH2:16][CH3:17])([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].Cl[CH2:19][CH2:20][CH2:21][CH2:22][S:23]([O-:26])(=[O:25])=[O:24].[C:27]1([O-:33])[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1.[Na+]>C1COCC1>[CH2:14]([N+:5]([CH2:1][CH2:2][CH2:3][CH3:4])([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:10][CH2:11][CH2:12][CH3:13])[CH2:15][CH2:16][CH3:17].[O:33]([CH2:19][CH2:20][CH2:21][CH2:22][S:23]([O-:26])(=[O:25])=[O:24])[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1

Participants

4

Reactant 2

HCID 4445035Phenolate SodiumHCID 86654806HCID 86654806, compound

Product 1

HCID 86654805HCID 86654805, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent2×

Procedure

To a solution of tetrabutylammonium-4-chlorobutylsulfonate in THF a solution of sodium phenolate in THF is added dropwise under cooling. After complete addition, the solution is allowed to warm to room temperature. The precipitate is filtered off and the remaining solution is concentrated with a rotary evaporator to yield tetrabutylammonium-4-phenoxybutylsulfonate.

Workup

  1. temperatureunder cooling
  2. additionAfter complete addition
  3. filtrationThe precipitate is filtered off
  4. concentrationthe remaining solution is concentrated with a rotary evaporator

Sources & evidence

ORD record
ord-28b188bfb5b5459b9bc31049714053a8
Source dataset
uspto-grants-2014_02
Patent number
US08642778B2

Reaction notes

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