Azobisisobutyronitrile → HCID 53984011, compound

HRID 2395595Notes

Reaction equation

HRID 2395595 reaction equation
[Br:1][C:2]1[CH:3]=[CH:4][C:5]([F:11])=[C:6]([CH:8]=[CH:9][CH3:10])[CH:7]=1.N(C(C)(C)C#N)=NC(C)(C)C#N.[Br:24]N1C(=O)CCC1=O>C(Cl)(Cl)(Cl)Cl>[Br:1][C:2]1[CH:3]=[CH:4][C:5]([F:11])=[C:6]([CH:8]=[CH:9][CH2:10][Br:24])[CH:7]=1

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 67184N-bromobutanimideHCID 53854056HCID 53854056, compound

Product 1

HCID 53984011HCID 53984011, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

A mixture of 4.3 g (0.02 mol) of 5-bromo-2-fluoro-1-(1-propenyl) benzene, 100 ml of carbon tetrachloride, 0.07 g of azobisisobutyronitrile and 3.6 g (0.02 mol) of N-bromosuccinimide is heated for 5 h at reflux. The solid is filtered, the filtrate is evaporated under vacuum and the residue used without other purification in the following stage: Yd.: 5.4 g (91%)

Workup

  1. temperatureis heated for 5 h
  2. temperatureat reflux
  3. filtrationThe solid is filtered
  4. customthe filtrate is evaporated under vacuum
  5. customthe residue used without other purification in the following stage

Sources & evidence

ORD record
ord-047fcb89284e4b3abaed5a4cb93dea21
Source dataset
uspto-grants-1996_02
Patent number
US05489592

Reaction notes

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