4-Nitrobenzaldehyde → HCID 53810778, compound

HRID 2395774Notes

Reaction equation

HRID 2395774 reaction equation
[N+:1]([C:4]1[CH:11]=[CH:10][C:7]([CH:8]=O)=[CH:6][CH:5]=1)([O-:3])=[O:2].[N:12]([CH2:15][C:16]([O:18][CH3:19])=[O:17])=[N+:13]=[N-:14]>>[CH3:19][O:18][C:16](=[O:17])[C:15]([N:12]=[N+:13]=[N-:14])=[CH:8][C:7]1[CH:10]=[CH:11][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=1

Participants

3

Reactant 2

HCID 5414-NitrobenzaldehydeHCID 4020482Methyl 2-azidoacetate

Product 1

HCID 53810778HCID 53810778, compound

Procedure

Following the general procedure of PREPARATION 61 and making non-critical variations but starting with p-nitrobenzaldehyde (10 g) and methyl azidoacetate (30.4 g), the title compound is obtained, NMR 8.34, 8.07, 7.02, and 4.07 δ.

Workup

  1. customthe general procedure of PREPARATION 61

Sources & evidence

ORD record
ord-0893cd21750b4cfa91c8b8367b5acba7
Source dataset
uspto-grants-1996_02
Patent number
US05489593

Reaction notes

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