HCID 4532, compound → HCID 53837090, compound

HRID 2396924Notes

Reaction equation

HRID 2396924 reaction equation
[CH2:1]([C:3]([CH:18]([N+:20]([O-:22])=[O:21])[CH3:19])=[CH:4][C:5](=[N:16][OH:17])[CH2:6][NH:7][C:8]([C:10]1[CH:11]=[N:12][CH:13]=[CH:14][CH:15]=1)=[O:9])[CH3:2].ClC1C=CC=C(C(OO)=[O:31])C=1.C(Cl)(Cl)Cl>CC(C)=O>[CH2:1]([C:3]([CH:18]([N+:20]([O-:22])=[O:21])[CH3:19])=[CH:4][C:5](=[N:16][OH:17])[CH2:6][NH:7][C:8]([C:10]1[CH:11]=[N+:12]([O-:31])[CH:13]=[CH:14][CH:15]=1)=[O:9])[CH3:2]

Participants

5

Reactant 3

HCID 4532HCID 4532, compoundHCID 6212ChloroformHCID 70297m-Chloroperbenzoic acid

Product 1

HCID 53837090HCID 53837090, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

A mixture of N-(4-ethyl-2-hydroxyimino-5-nitro-3-hexen-1-yl)-3-pyridinecarboxamide (306 mg), 3-chloroperbenzoic acid (323 mg), chloroform (15 ml) and acetone (40 ml) was stirred at room temperature for 10 hours. The resulting precipitates were collected and washed with acetone to give N-(4-ethyl-2-hydroxyimino-5-nitro-3-hexen-1-yl)-3-pyridinecarboxamide 1-oxide.

Workup

  1. customThe resulting precipitates
  2. customwere collected
  3. washwashed with acetone

Sources & evidence

ORD record
ord-19655a1247d74b8ba6be2d9fb62e4be5
Source dataset
uspto-grants-1996_02
Patent number
US05495023

Reaction notes

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