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HRID2397900

反应详情

EQUATION

反应方程式

HRID 2397900 的结构方程式

REACTANTS

反应物

4
结构：CCO
HCID702

Ethanol

C2H6O

结构：CC(C)O
HCID3776

Isopropanol

C3H8O

结构：CC(C)OC(=O)CC(=N)N
HCID12391080

未命名化合物

结构：COC(=O)CC(=O)C=Cc1ccccc1[N+](=O)[O-]
HCID53723829

Methyl 5-(2-nitrophenyl)-3-oxopent-4-enoate

C12H11NO5

PRODUCTS

生成物

1
结构：COC(=O)C1=C(C)NC(N)=C(C(=O)OC(C)C)C1c1ccccc1[N+](=O)[O-]
HCID70635723

未命名化合物

收率 50%

PROCEDURE

实验过程

Upon heating a solution of 12.5 g of 2-nitrobenzylideneacetoacetic acid methyl ester and 7.2 g of amidinoacetic acid isopropyl ester in 100 ml of ethanol for 8 hours, 2-amino-6-methyl-4-(2 -nitrophenyl)-1,4-dihydropyridine-3,5-dicarboxylic acid 3-isopropyl ester 5-methyl ester of melting point 203° C. (isopropanol) is obtained. Yield: 50% of theory.