Octane → HCID 12783668, compound

HRID 2398707Notes

Reaction equation

HRID 2398707 reaction equation
[CH:1]1[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1.[OH-].[Na+].CCCCCCCC.[I-].C[P+](C)(C)C.[Cl:31][CH2:32][Cl:33]>C(Cl)(Cl)Cl>[Cl:31][C:32]1([Cl:33])[CH:14]2[CH:1]1[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13]2

Participants

7

Reactant 5

HCID 356OctaneHCID 6344DichloromethaneHCID 14798Sodium HydroxideHCID 120511Tetramethylphosphanium iodideHCID 138767HCID 138767, compound

Product 1

HCID 12783668HCID 12783668, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Cyclotetradecene (4.0 g), chloroform (18 ml), 50% aqueous sodium hydroxide solution (22 ml), dichloromethane (5 ml), n-octane (1 ml) and tetramethylphosphonium iodide (0.01 g) were stirred together at 35° C. for 3 hours. At the end of this period the conversion of starting material to the desired product was found by GLC to be 100%.

Sources & evidence

ORD record
ord-5f5ee7364deb44bd82132d9659134717
Source dataset
uspto-grants-1977_05
Patent number
US04025562

Reaction notes

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