Octane → HCID 12323991, compound

HRID 2398709Notes

Reaction equation

HRID 2398709 reaction equation
[CH:1]1[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1.[OH-].[Na+].[Cl:15][CH:16]([Cl:18])C.C(OS([O-])(=O)=O)C.C([S+](C(CCCCCCCCCC)C)CC)(CCCCCCCCCCCCCC)C.CCCCCCCC>C(Cl)(Cl)Cl>[Cl:15][C:16]1([Cl:18])[CH:12]2[CH:1]1[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]2

Participants

7

Reactant 5

HCID 356OctaneHCID 63651,1-DichloroethaneHCID 14798Sodium HydroxideHCID 15164Cyclododecene, (E)-HCID 20289373HCID 20289373, compound

Product 1

HCID 12323991HCID 12323991, compoundYield 98%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Cyclododecene (41.5 g), chloroform (225 ml), 50% aqueous sodium hydroxide solution (275 ml), dichloroethane (60 ml), sec-hexadecyl sec-dodecyl ethylsulphonium ethylsulphate (0.3 g) and n-octane (12 ml) were stirred together at ambient temperature for 10 hours. The product was recovered in a similar manner to that described in Example I(b) (yield 98%)

Workup

  1. customThe product was recovered in a similar manner to that

Sources & evidence

ORD record
ord-507f8e9bbab3494e887b689a82439e56
Source dataset
uspto-grants-1977_05
Patent number
US04025562

Reaction notes

Loading…