Didecyldimethylammonium Chloride → HCID 69295561, compound

HRID 2403129Notes

Reaction equation

HRID 2403129 reaction equation
[Cl-].[CH2:2]([N+:12]([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([CH3:14])[CH3:13])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[Na+].[C:26]([O-:34])(=[O:33])[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1>O>[C:26]([O-:34])(=[O:33])[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1.[CH2:15]([N+:12]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])([CH3:14])[CH3:13])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

Participants

4

Reactant 2

HCID 23558Didecyldimethylammonium ChlorideHCID 517055Sodium Benzoate

Product 1

HCID 69295561HCID 69295561, compoundYield 85%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
80 °C

Procedure

Didecyldimethylammonium chloride (0.02 mol) was dissolved in distilled water and 0.015 mol of benzoic acid sodium salt was added. The solution was stirred at 80° C. for 7 h. The reaction mixture was extracted by chloroform. Chloroform phase was removed and washed with distilled, cold water until chloride ions were no longer detected using AgNO3. Then chloroform was removed. Obtained benzoate in 85% yield was dried in vacuum. 1H NMR and 13C NMR (CDCl3) were obtained.

Workup

  1. extractionThe reaction mixture was extracted by chloroform
  2. customChloroform phase was removed
  3. washwashed
  4. distillationwith distilled
  5. customThen chloroform was removed
  6. dry with materialObtained benzoate in 85% yield was dried in vacuum
  7. custom1H NMR and 13C NMR (CDCl3) were obtained

Sources & evidence

ORD record
ord-4370f733472445ff863b22552ba52bcc
Source dataset
uspto-grants-2014_08
Patent number
US08802596B2

Reaction notes

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