Dimethylamine → HCID 123262017, compound

HRID 2412351Notes

Reaction equation

HRID 2412351 reaction equation
CCCCC.Cl[SiH](Cl)Cl.[CH3:10][NH:11][CH3:12].[CH2:13]([O:15][SiH:16]([O:18][CH2:19][CH3:20])Cl)[CH3:14]>C(O)C>[CH2:13]([O:15][SiH:16]([O:18][CH2:19][CH3:20])[N:11]([CH3:12])[CH3:10])[CH3:14]

Participants

6

Reactant 4

HCID 674DimethylamineHCID 8003PentaneHCID 24811TrichlorosilaneHCID 80978Diethoxychlorosilane

Product 1

HCID 123262017HCID 123262017, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Following the same general procedure described in Example 1, 2 liters of pentane and 404 mls of trichlorosilane were charged in a 5 L flask. During reflux, 464 mls of anhydrous ethanol was added dropwise. After the alcoholysis was completed, 550 mls of dimethylamine was added to the unisolated diethoxychlorosilane. Distillation yielded 290 g of diethoxy(dimethylamino)silane (b.p. 138°-139° C.).

Workup

  1. additionwere charged in a 5 L flask
  2. temperatureDuring reflux
  3. distillationDistillation

Sources & evidence

ORD record
ord-e9cf11db6d9347cf917c42109a56b8eb
Source dataset
uspto-grants-1985_01
Patent number
US04491669

Reaction notes

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