Methyl p-toluenesulfonate → HCID 20430711, compound

HRID 2413318Notes

Reaction equation

HRID 2413318 reaction equation
[C:1]1([As:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:20]1([CH3:31])[CH:25]=[CH:24][C:23]([S:26]([O:29]C)(=[O:28])=[O:27])=[CH:22][CH:21]=1>>[C:20]1([CH3:31])[CH:21]=[CH:22][C:23]([S:26]([O-:29])(=[O:27])=[O:28])=[CH:24][CH:25]=1.[CH3:20][As+:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

Participants

3

Reactant 2

HCID 6645Methyl p-toluenesulfonateHCID 11773Triphenylarsine

Product 1

HCID 20430711HCID 20430711, compound

Procedure

A mixture of 50.0 g (0.1632 mol) of triphenylarsine and 30.4 g (0.1632 mol) of methyl p-toluenesulfonate was heated in a 125°-145° C. bath under nitrogen with stirring for 1 hr and cooled. The glassy solid was crystallized by treatment with ether, collected and dried.

Workup

  1. temperaturewas heated in a 125°-145° C. bath under nitrogen
  2. temperaturecooled
  3. customThe glassy solid was crystallized by treatment with ether
  4. customcollected
  5. customdried

Sources & evidence

ORD record
ord-092a9e66ac4949feac19a108afc2e5e1
Source dataset
uspto-grants-1985_01
Patent number
US04496643

Reaction notes

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