Methyl p-toluenesulfonate → HCID 20430720, compound

HRID 2413319Notes

Reaction equation

HRID 2413319 reaction equation
[C:1]1([Sb:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:20]1([CH3:31])[CH:25]=[CH:24][C:23]([S:26]([O:29]C)(=[O:28])=[O:27])=[CH:22][CH:21]=1>>[C:20]1([CH3:31])[CH:21]=[CH:22][C:23]([S:26]([O-:29])(=[O:27])=[O:28])=[CH:24][CH:25]=1.[CH3:20][Sb+:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

Participants

3

Reactant 2

HCID 6645Methyl p-toluenesulfonateHCID 11777Triphenylstibine

Product 1

HCID 20430720HCID 20430720, compound

Conditions

Temperature
130 °C

Procedure

A mixture of 17.65 g (0.05 mol) of triphenylstibine and 9.31 g (0.05 mol) of methyl p-toluenesulfonate was heated in a 130° C. bath with nitrogen bubbling through the melt for 18 hr. The resulting syrup was cooled to an amorphous glass which was crystallized by treatment with ether. The resultant crystals were collected and dried.

Workup

  1. temperatureThe resulting syrup was cooled to an amorphous glass which
  2. customwas crystallized by treatment with ether
  3. customThe resultant crystals were collected
  4. customdried

Sources & evidence

ORD record
ord-8320cbeb6e56435d802eb3c8adb0e549
Source dataset
uspto-grants-1985_01
Patent number
US04496643

Reaction notes

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