Hydrochloric Acid → HCID 54509253, compound

HRID 2417748Notes

Reaction equation

HRID 2417748 reaction equation
[CH2:1]([C:3]([CH:10]([CH2:12][CH3:13])[CH3:11])([C:7](O)=[O:8])[C:4](O)=[O:5])[CH3:2].S(Cl)([Cl:16])=O.[ClH:18]>C(OCC)C>[CH2:1]([C:3]([CH:10]([CH2:12][CH3:13])[CH3:11])([C:7]([Cl:16])=[O:8])[C:4]([Cl:18])=[O:5])[CH3:2]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 24386Thionyl ChlorideHCID 2314574372-17-2

Product 1

HCID 54509253HCID 54509253, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To dry ethyl ether (55.0 ml) under nitrogen was added ethyl 2-(2-butyl)malonic acid (55.0 g, 0.29 mole). Thionyl chloride (32.0 ml, 52.5 g, 0.44 mole) was added dropwise with stirring. The solution was heated to 50° C. for 2 hours under nitrogen, at which time no further HCl was evolved.

Sources & evidence

ORD record
ord-b683ba0db4b3439f84b7b2a075f4f89c
Source dataset
uspto-grants-1984_09
Patent number
US04470421

Reaction notes

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