Methane → HCID 86739656, compound

HRID 2418642Notes

Reaction equation

HRID 2418642 reaction equation
[C:1]1([NH:7][CH2:8][C:9]([OH:11])=O)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:12]([N:15]=[C:16]=[S:17])[CH:13]=[CH2:14].C>>[C:1]1([N:7]2[CH2:8][C:9](=[O:11])[N:15]([CH:12]=[CH:13][CH3:14])[C:16]2=[S:17])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 3

HCID 297MethaneHCID 5971Allyl IsothiocyanateHCID 66025N-Phenylglycine

Product 1

HCID 86739656HCID 86739656, compoundYield 31.3%

Procedure

A mixture of N-phenyl glycine (15.1 grams, 0.1 moles) and allylisothiocyanate (12.0 grams, 0.12 moles) was refluxed for 6 hours and allowed to stand overnight at room temperature (21° C.). The reaction mixture became a solid mass which was ground and crystallized from ethanol using charcoal, 7.26 grams (31% yield) of the above-identified product was recovered having a melting point of about 74° C.

Workup

  1. temperaturewas refluxed for 6 hours
  2. custom(21° C.)
  3. customcrystallized from ethanol

Sources & evidence

ORD record
ord-1997169657254426abf3f595b4727598
Source dataset
uspto-grants-1984_09
Patent number
US04473393

Reaction notes

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