Nitrogen → HCID 88806605, compound

HRID 2418961Notes

Reaction equation

HRID 2418961 reaction equation
[C:1](=[O:16])([O:9]C1C=CC=CC=1)[O:2]C1C=CC=CC=1.[CH3:17][C:18]1[C:24]([CH3:25])=[C:23]([OH:26])[C:22]([CH3:27])=[CH:21][C:19]=1[OH:20].C(=O)([O-])[O-].[K+].[K+].N#N.C1(O)C=CC=CC=1>>[C:1](=[O:2])([OH:16])[OH:9].[CH3:27][C:22]1[C:23]([OH:26])=[C:24]([CH3:25])[C:18]([CH3:17])=[C:19]([CH:21]=1)[OH:20]

Participants

6

Reactant 5

HCID 947NitrogenHCID 996PhenolHCID 7597Diphenyl carbonateHCID 11430Potassium CarbonateHCID 12785Trimethylhydroquinone

Product 1

HCID 88806605HCID 88806605, compound

Procedure

21.4g (0.1 mole) of diphenyl carbonate, 18.2g (0.12 mole) of 2,3,5-trimethylhydroquinone and 0.1g of potassium carbonate were heated and stirred under the N2 -gas atmosphere at 150° C for 3 hours. After this, phenol was distilled off and the residue solidified to obtain a glassy solid. Distilled phenol was 105% of calculated quantity. M. P.: 97°-103° C, molecular weight: 975 (calculated value 1047).

Workup

  1. distillationAfter this, phenol was distilled off
  2. customto obtain a glassy solid

Sources & evidence

ORD record
ord-505d7807de7943379949f4e368942560
Source dataset
uspto-grants-1978_08
Patent number
US04104217

Reaction notes

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